Prášek ze slitiny TiNb

Introduction to TiNb Alloy Powder

TiNb alloy powder is composed of titanium and niobium metals. It offers a unique combination of high strength, low density, biocompatibility, corrosion resistance, fatigue and creep resistance at high temperatures.

TiNb alloys are part of a broader class of titanium intermetallic materials that have superior physical, chemical and mechanical properties compared to pure titanium. The addition of niobium as an alloying element enhances certain properties and allows tailoring TiNb alloys for specific applications.

Some key advantages of TiNb alloy powder include:

• Vysoký poměr pevnosti a hmotnosti
• Ability to withstand extreme temperatures and stresses
• Resists wear, abrasion and corrosion in harsh environments
• Biokompatibilní a netoxické pro lékařské použití
• Can be processed into complex shapes using additive manufacturing
• Provides design flexibility for engineers

TiNb alloys compete with nickel and cobalt-based superalloys in the aerospace industry. They also offer an alternative to stainless steels for biomedical implants and devices. TiNb alloys are enabling new applications and designs not possible with other materials.

This article provides a technical reference covering the composition, properties, processing, applications, specifications, costs and other practical aspects of TiNb alloy powder.

TiNb Alloy Powder Composition

TiNb alloys contain primarily titanium and niobium as the key constituent elements. The niobium content typically ranges from 10% to 50% by weight, with the balance being titanium.

The ratio of Ti to Nb can be adjusted to create different grades of TiNb alloys optimized for certain properties. Some common TiNb grades include:

• Ti-10Nb – 10% niobium, 90% titanium
• Ti-35Nb – 35% niobium, 65% titanium
• Ti-45Nb – 45% niobium, 55% titanium
• Ti-50Nb – 50% niobium, 50% titanium

Additionally, small amounts of other elements like zirconium, tantalum, molybdenum, chromium may be added to further enhance properties. Oxygen and nitrogen may also be present as impurities.

Table 1: Chemical composition of common TiNb alloy grades

Stupeň slitiny	Niobium Content	Obsah titanu
Ti-10Nb	10%	90%
Ti-35Nb	35%	65%
Ti-45Nb	45%	55%
Ti-50Nb	50%	50%

Controlling the composition is critical to achieve the desired properties in the final TiNb alloy product. Powder metallurgy techniques allow precise mixing of the constituent metals into an alloy powder feedstock.

TiNb Alloy Powder Properties

TiNb alloys exhibit a range of useful physical, mechanical and chemical properties that make them suitable for high performance applications. Some key properties include:

Fyzikální vlastnosti

• Density – 4.5 to 5.5 g/cm3, lower than steel and nickel alloys
• Melting point – 1550 to 1750°C depending on composition
• Electrical resistivity – 0.5 to 0.6 μΩ.m, higher than pure titanium
• Thermal conductivity – 6 to 22 W/m.K, lower than titanium

Mechanické vlastnosti

• Tensile strength – 500 to 1100 MPa, increases with niobium content
• Yield strength – 300 to 900 MPa
• Elongation – 10% to 25%
• Hardness – 200 to 350 HV
• Fatigue strength – 400 to 600 MPa

Other Properties

• Corrosion resistance – Excellent due to protective oxide layer
• Wear resistance – Better than titanium due to hardness
• Biocompatibility – Non-toxic and non-allergenic

By adjusting the Ti/Nb ratio, properties like strength, ductility, hardness and elastic modulus can be optimized as per application requirements.

Table 2: Typical properties of Ti-35Nb alloy

Vlastnictví	Hodnota
Hustota	5.2 g/cm3
Bod tání	1600°C
Pevnost v tahu	650 MPa
Pevnost v tahu	550 MPa
Prodloužení	15%
Elastic modulus	60 GPa
Tvrdost	250 HV

TiNb Alloy Powder Applications

The unique properties of TiNb alloys make them suitable for demanding applications in various industries:

Aerospace

• Engine components – blades, discs, fasteners
• Airframe parts – landing gear, wings, fuselage
• Hydraulic systems – pumps, valves, actuators

Automobilový průmysl

• Valve springs, engine valves
• Connecting rods, turbocharger rotors
• Motor racing components

Biomedicína

• Orthopedic implants – knee, hip
• Dental implants, crowns
• Chirurgické nástroje
• Zdravotnické prostředky

Chemický průmysl

• Heat exchangers, reactors
• Pumps, valves, pipes
• Zařízení odolné proti korozi

Další aplikace

• Sporting goods – golf clubs, bike frames
• High-end watches and jewelry
• Electrical contacts and connectors
• High temperature furnace parts

The combination of strength, temperature resistance, corrosion resistance and biocompatibility allows TiNb alloys to substitute heavier materials across these industries.

Table 3: TiNb alloy applications by industry

Průmysl	Aplikace
Aerospace	Engine components, airframe parts, hydraulic systems
Automobilový průmysl	Valve springs, engine valves, connecting rods
Biomedicína	Implants, dental, surgical instruments, devices
Chemické	Heat exchangers, reactors, pumps, valves
Další	Sporting goods, watches, electrical contacts, furnace parts

TiNb Alloy Powder Processing

TiNb alloy powder can be produced via different processing routes:

Metal Powder Blending

• elemental titanium and niobium powders are blended together in the required composition
• blended powder mixture is mechanically alloyed to form the TiNb alloy powder

Atomizace plynu

• molten TiNb alloy is atomized with an inert gas into fine droplets
• droplets solidify into spherical alloy powder particles

Proces plazmové rotující elektrody (PREP)

• TiNb electrode rod is melted using plasma arc and spun at high speeds
• centrifugal force causes droplets to break off and solidify into particles

Hydride-Dehydride (HDH) Method

• Ti and Nb metals are converted into brittle hydride powders
• hydride powders are blended, dehydrided, crushed and sieved

The particle size, morphology, flowability and microstructure of the powder can be controlled by selecting the appropriate manufacturing process. This influences the final properties after consolidation.

Table 4: TiNb alloy powder production methods

Metoda	Popis	Velikost částic	Morfologie
Mechanické legování	Blending and milling Ti and Nb powders	10 - 50 mikronů	Nepravidelné, hranaté
Rozprašování plynu	Inert gas atomization of molten alloy	15 - 150 mikronů	Sférické
Plasma rotating electrode	Centrifugal disintegration of melted electrode	50 - 150 mikronů	Sférické
HDH process	Hydriding, dehydriding, crushing blended powders	10 – 63 microns	Nepravidelné, hranaté

Consolidation of TiNb Alloy Powder

TiNb alloy powder can be converted into full-density components using various powder metallurgy consolidation techniques:

Izostatické lisování za tepla (HIP)

• encapsulated powder is HIPped at high temperature and pressure

Vacuum Sintering

• powder is compacted and sintered in vacuum furnace

Spark Plasma Sintering

• powder is simultaneously heated and compressed by pulsed DC current

Vstřikování kovů (MIM)

• powder is mixed with binder, molded, debinded and sintered

Aditivní výroba

• powder bed fusion (SLM, EBM) or directed energy deposition (DED)

HIP and vacuum sintering can achieve close to full density while retaining fine microstructure. Additive manufacturing offers greater geometric freedom. The consolidation process can be optimized to achieve the desired properties.

Table 5: TiNb alloy powder consolidation techniques

Metoda	Popis	Hustota	Mikrostruktura	Geometrie
HIP	High pressure, high temperature	Near full density	Pokuta	Simple shapes
Vakuové spékání	Sintering in vacuum furnace	Near full density	Pokuta	Simple shapes
Spékání jiskrovou plazmou	Pulsed current and pressure	Full density	Ultrafine	Simple shapes
Vstřikování kovů	Powder + binder molding	Near full density	Ultrafine	Složité tvary
Aditivní výroba	Powder bed fusion or directed energy deposition	Near full density	Hrubý	Složité tvary

Specifications for TiNb Alloy Powder

TiNb alloy powder is available in various specifications tailored for different applications:

Compositions: Grades with 10% to 50% niobium content

Velikost částic: 10 až 150 mikronů

Morfologie: Spherical, irregular or blended

Production Method: Gas atomized, HDH, blended elemental

Čistota: >99.5% titanium, >99.8% niobium

Obsah kyslíku: <2000 ppm

Tekutost: Hall flow rate > 23 sec/50g

Zdánlivá hustota: ≥ 2,5 g/cc

Hustota kohoutku: ≥ 3,5 g/cc

Chemical composition, particle size distribution, morphology, flow rate and density are commonly specified properties. Custom alloys and powder specifications can be produced for specific applications.

Table 6: Typical specification of Ti-35Nb gas atomized powder

Parametr	Specifikace
Složení slitiny	Ti-35Nb
Velikost částic	15 až 45 mikronů
Morfologie	Sférické
Způsob výroby	Rozprašování plynu
Čistota	Ti >99.5%, Nb >99.8%
Obsah kyslíku	<1500 ppm
Průtoková rychlost	>38 sec/50g
Zdánlivá hustota	≥ 2.7 g/cc
Hustota poklepání	≥ 4.2 g/cc

Suppliers of TiNb Alloy Powder

Some leading global suppliers of titanium niobium alloy powder include:

• AP&C – titanium and niobium alloy powders
• Atlantic Equipment Engineers – spherical and angular powders
• TLS Technik – gas atomized TiNb alloys
• Metal Technology – blended elemental and prealloyed powders
• Sandvik Osprey – gas atomized spherical powders
• Carpenter Additive – customized alloy powders

TiNb alloys are also offered by suppliers of titanium and niobium metals. Both standardized alloys and custom compositions can be sourced from these powder producers.

Table 7: TiNb alloy powder suppliers

Společnost	Materiály	Výrobní metody
AP&C	Ti, Nb, TiNb alloys	Rozprašování plynu
Atlantik vybavení inženýrů	Ti, Nb, TiNb alloys	Gas atomization, blending
Technika TLS	TiNb alloys	Rozprašování plynu
Technologie kovů	TiNb alloys	Blended elemental, prealloyed
Sandvik Osprey	TiNb alloys	Rozprašování plynu
Přísada pro tesaře	Custom TiNb alloys	Rozprašování plynu

Cost of TiNb Alloy Powder

TiNb alloy powder is more expensive than titanium or niobium powder alone. Cost depends on:

• Composition – higher Nb content increases cost
• Purity – cost increases for higher purity
• Velikost a distribuce částic
• Production method – gas atomized powder costs more
• Order quantity – larger volumes have lower cost

Indicative pricing for TiNb alloy powder in small quantities:

• Ti-10Nb: $100 to $300 per kg
• Ti-35Nb: $200 to $500 per kg
• Ti-50Nb: $300 to $800 per kg

Pricing reduces significantly for bulk orders of hundreds of kilos or several tons.

Table 8: Indicative pricing of TiNb alloy powders

Slitina	Pricing ($/kg)
Ti-10Nb	$100 – $300
Ti-35Nb	$200 – $500
Ti-50Nb	$300 – $800

Handling and Storage of TiNb Alloy Powder

As a reactive metallic powder, some care is needed when handling TiNb alloy powder:

• Store in sealed containers in a dry, inert atmosphere to prevent oxidation and contamination
• Avoid contact with oxygen, moisture, oils, combustible materials
• Prevent accumulation of fine powders on surfaces or equipment
• Ground all conductive equipment used in handling
• Use spark-proof tools and minimize dust generation
• Wear gloves and respiratory protection when handling
• Use grounded ventilation systems and avoid dust clouds
• Keep away from heat, flames, sparks and other ignition sources
• Follow safety data sheet for proper PPE and precautions

If stored properly in a dry, inert atmosphere, TiNb alloy powder has a typical shelf life of 12 months. Improper storage conditions can lead to oxidation, loss of flowability, or ignition hazards.

Table 9: TiNb alloy powder handling guidelines

Parametr	Pokyny
Úložiště	Sealed containers, dry inert atmosphere
Atmosféra	Avoid oxygen, moisture, oils, combustibles
Zařízení	Ground all conductive equipment
Nástroje	Používejte nejiskřící nástroje
Ventilace	Grounded ventilation system
PPE	Gloves, respiratory protection
Precautions	Avoid heat, flames, sparks
Doba skladování	12 months in inert atmosphere

Safety Data Sheet for TiNb Alloy Powder

Like other reactive metal powders, some important safety precautions for TiNb alloy:

• Wear PPE – gloves, eye protection, mask/respirator
• Avoid inhalation of powders – use respiratory protection
• Vyhněte se kontaktu s kůží a očima
• Wash thoroughly after handling powder
• Avoid ignition sources, powders may be flammable
• Use proper grounding and ventilation
• Inert storage atmosphere to prevent oxidation
• Avoid spills and dust accumulation on surfaces
• Follow instructions on SDS and warning labels

First aid:

• Inhalation: Move to fresh air. Get medical help if needed.
• Skin contact: Wash with soap and water. Get help if irritation persists.
• Eye contact: Flush eyes with water for 15 minutes. Get medical attention.
• Ingestion: Drink water. Get medical assistance if discomfort occurs.

Always refer to SDS from supplier for complete health and safety information before handling and processing TiNb alloy powder.

Table 10: Key safety measures for TiNb alloy powder

Safety Item	Precautions
PPE	Gloves, goggles, N95 mask
Inhalation	Use respiratory protection
Skin contact	Wash affected area with soap and water
Eye contact	Flush eyes with water for 15 minutes
Ingestion	Drink water. Get medical help if needed.
Ventilace	Use grounded ventilation hoods
Uzemnění	Ground all equipment during handling
Ignition	Avoid sparks, flames, heat sources
Úložiště	Inert atmosphere away from flammable materials

Quality Inspection of TiNb Alloy Powder

To ensure TiNb alloy powder meets specifications, various quality checks are performed:

• Chemická analýza – ICP, GDMS or LECO analysis to verify composition and purity
• Analýza velikosti částic – laser diffraction or sieve analysis for size distribution
• Morfologie – SEM imaging to check particle shape and surface topology
• Průtoková rychlost – Hall flow meter test for powder flowability
• Hustota – apparent density and tap density measurements
• Kyslík/dusík – inert gas fusion analysis for interstitial impurities
• Phase identification – XRD analysis to determine phases present

Powder properties are tested on each batch to quality standards like ASTM B939, ASTM F3049, EN 10204 3.1. Powder can be blended between lots to achieve uniformity.

Table 11: Testing methods for TiNb alloy powder

Test	Metoda	Standard
Složení	ICP, GDMS, LECO	ASTM E1479, ASTM E2330
Distribuce velikosti částic	Laserová difrakce, prosévání	ASTM B822
Morfologie	Zobrazování pomocí SEM	ASTM B822
Průtoková rychlost	Hall flow meter	ASTM B213
Hustota	Volumetr Scott	ASTM B212
Oxygen/Nitrogen	Fúze inertních plynů	ASTM E1019
Phase analysis	Difrakce rentgenového záření	ASTM E1876

Medical Applications of TiNb Alloy

Due to their biocompatibility, high strength and low modulus, TiNb alloys are widely used for medical implants and devices:

Ortopedické implantáty

• Knee and hip replacements
• Bone plates, screws
• Spinal fixation devices
• Dental implants and bridges

TiNb alloys like Ti-35Nb and Ti-45Nb match the elastic modulus of human bone while providing high fatigue strength. This reduces stress shielding compared to stiffer titanium alloys.

Cardiovascular Devices

• Stenty
• Pacemaker casings
• Guidewires
• Chirurgické nástroje

The corrosion resistance, non-toxicity and non-magnetism of TiNb alloys make them suitable for devices that contact blood and tissues.

TiNb Alloy Grades for Medical Use

• Ti-10Nb to Ti-50Nb
• Ti-Nb-Zr, Ti-Nb-Ta for adjusted properties
• ISO 5832-11 and ASTM F2066 standards

Lower modulus Ti-35Nb and Ti-45Nb are commonly used. Higher Nb strengthens but increases modulus. Small Zr/Ta additions further tailor properties.

Advantages of TiNb Alloys for Biomedical Use

• Excellent biocompatibility and osseointegration
• High strength and fatigue resistance
• Low modulus close to bone
• Non-toxic, non-allergenic
• Odolnost proti korozi
• Nemagnetické

TiNb alloys provide the best combination of strength, biocompatibility, corrosion resistance and elastic modulus for implants.

Challenges of TiNb Alloy Medical Components

• Difficult machining and fabrication
• Costlier than Ti-6Al-4V alloy
• Requires rigorous quality control and testing
• Longer-term clinical data still evolving

Being relatively new for medical use, manufacturing and licensing of TiNb components can be more complex. But their advantages outweigh short-term challenges.

Automotive Uses of TiNb Alloy

The high strength, temperature resistance and fatigue life of TiNb alloys make them attractive for automotive parts:

Valve Springs

• Higher strength allows lower spring mass
• Reduces valve float at high RPM
• Allows higher power output

Engine Valves

• Withstands high temperature exhaust gases
• Resists wear and deformation
• Lehká váha

Connecting Rods

• Vysoký poměr pevnosti a hmotnosti
• Reduces reciprocating mass
• Allows higher RPM and power

Turbocharger Rotors

• Zachovává pevnost při vysokých teplotách
• Resists creep deformation
• Thermal shock resistance
• Nízká hustota

Motor Racing Components

• Lightweight suspension, chassis parts
• Superior fatigue life

Reduced mass and inertia combined with temperature and fatigue resistance lead to higher engine performance and efficiency.

Challenges of TiNb Alloys for Automotive

• High cost compared to steel alloys
• Processing difficulties with powder metallurgy
• Limited suppliers and manufacturing experience
• Uncertain cost-benefit ratio

The benefits may justify premium pricing for high-end vehicles and motorsports initially. Broader adoption depends on TiNb powder producers driving down costs.

Aerospace Applications of TiNb Alloys

TiNb alloys compete with nickel superalloys for aircraft engine and airframe applications needing strength at low temperatures:

Součásti motoru

• Turbine blades, discs, casings
• Compressor blades
• Shafts, fasteners
• Thrust reversers

Konstrukční díly

• Podvozek
• Wings, ribs, stringers
• Fuselage frames
• Hydraulic tubing

Výhody

• 30-50% lower density than Ni superalloys
• Saves weight
• Similar strength and creep resistance
• Withstands high stresses and temperatures

Výzvy

• Higher costs than titanium alloys currently
• Processing difficulties compared to wrought alloys
• Limited production experience and availability
• Property data still evolving

The aerospace industry is conservative, so extensive testing and qualification programs are needed to prove viability and establish supply chains before adopting new alloys like TiNb.

Other Applications of TiNb Alloys

In addition to medical, automotive and aerospace uses, TiNb alloys are also suitable for:

• Marine – Propellers, pump shafts, fittings
• Chemical – Heat exchangers, condensers, piping
• Sporting goods – Golf clubs, bicycle frames, rackets
• Výroba energie - Komponenty parních a plynových turbín
• Electronics – Sputtering targets, capacitors
• Jewelry – Watches, rings, piercings
• Oil and gas – Downhole tools, valves, pumps

The corrosion resistance, biocompatibility and electrical properties expand the utility of TiNb alloys across diverse industries.

Continuing research and development will uncover new applications as manufacturing experience with TiNb alloy powder grows. Their unique balance of properties will enable designs not feasible with other materials.

Future Outlook for TiNb Alloys

• Expanding medical use driven by aging population and need for better implants
• Adoption in aerospace accelerating to reduce weight
• Automotive use escalating due to high performance needs
• Oil and gas interest rising for deep sea exploration hardware
• Manufacturing via powder metallurgy and AM techniques improving
• New grades being developed to tailor properties
• Supply chain expanding as producers add TiNb alloy capacity
• Costs declining with higher production volumes
• Broader awareness and acceptance across industries

The future looks bright for TiNb alloys to become a new advanced material that displaces traditional alloys in the most demanding applications. Their success hinges on continued investments to improve affordability.

Key Takeaways on TiNb Alloy Powder

• TiNb alloys offer superior mechanical properties compared to titanium
• Stronger, stiffer and higher hardness than pure titanium
• Lower density and higher strength than nickel/steel alloys
• Outstanding high temperature performance
• Resists creep, fatigue and corrosion in harsh environments
• Vynikající biokompatibilita pro lékařské implantáty
• Adjustable properties by changing Ti/Nb ratio
• Produced via blended elemental or prealloyed powder metallurgy
• Powder can be consolidated using AM, HIP, MIM or sintering
• Leading applications in aerospace, automotive, biomedical industries
• Future prospects positive driven by lightweighting and high performance needs

TiNb alloys represent an advanced metallic material breakthrough enabled by powder metallurgy techniques. As manufacturing costs decline, they are poised to disrupt several industries demanding lightweight, strong and temperature resistant alloys.

Frequently Asked Questions on TiNb Alloy Powder

Here are answers to some common questions about TiNb alloy powder:

Q: What are the main advantages of TiNb alloys over titanium alloys?

TiNb alloys have higher strength, stiffness, hardness, wear resistance, and high temperature performance compared to titanium alloys. They also have lower density than nickel and steel alloys.

Q: Which industries use TiNb alloys?

The main applications are in aerospace, automotive, biomedical, chemical, marine, and power generation industries. Usage is expanding as powder metallurgy production increases.

Q: What is the typical price range of TiNb alloy powder?

Pricing ranges from around $100/kg for Ti-10Nb to $300-800/kg for Ti-50Nb depending on composition, quality and order volume. Prices are declining as production expands.

Q: What particle size is common for TiNb alloy powder?

Particle sizes from 10 to 150 microns are typical. Fine powders 10-45 microns are preferred for additive manufacturing. Coarser up to 150 micron powders are used for press and sinter applications.

Q: How are TiNb alloy powders produced?

Main production methods include gas atomization, plasma spheroidization, hydride-dehydride process, and blended elemental. Gas atomized and plasma spheroidized powders have spherical morphology preferred for AM.

Q: What standards apply to TiNb alloys in medical use?

ISO 5832-11 and ASTM F2066 standards cover the composition, mechanical properties, quality control testing and processing requirements for surgical implant grade TiNb alloys.

Q: Can TiNb alloys be 3D printed?

Yes, TiNb alloy powders are compatible with laser powder bed fusion, electron beam powder bed fusion and directed energy deposition 3D printing processes. Parameters need optimization for good density and properties.

Q: Are there health risks associated with TiNb powders?

Like other metal powders, certain precautions are needed when handling TiNb powders to minimize dust explosion risks and inhalation exposures. But the alloy itself is highly biocompatible.

Q: What is the outlook for adoption of TiNb alloys?

The future looks promising with expanding use of TiNb alloys driven by the need for lightweight, strong and heat resistant materials. Adoption will accelerate as powder metallurgy production costs decrease.

This covers the key questions engineers have regarding specification, processing, applications and the prospects of TiNb alloy powder as an emerging advanced material. Reach out for any other specific queries.