Nickellegering HX pulver
Nickel Alloy HX-pulver kan användas för att tillverka komplexa komponenter med nätform med hjälp av additiva tillverkningsprocesser med pulverbäddsfusion som selektiv lasersmältning (SLM) och elektronstrålesmältning (EBM). Dess egenskaper gör den lämplig för delar som kräver hög hållfasthet, värmebeständighet och korrosionsbeständighet inom en rad olika branscher som flyg, olja och gas, fordonsindustri och allmän industri.
Legeringssystemet gör det möjligt att skräddarsy egenskaperna genom värmebehandling. Lösningsglödgning följt av åldring gör det möjligt att optimera hållfasthet, duktilitet och sprickmotstånd enligt applikationskraven.
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Översikt
Nickel Alloy HX powder is a nickel-chromium-iron-molybdenum alloy powder designed for additive manufacturing applications requiring high strength, corrosion resistance, and high temperature capability. Some key properties of Nickel Alloy HX powder include:
Nickel Alloy HX Powder Key Properties
Fastighet | Beskrivning |
---|---|
Sammansättning | Nickel, chromium, iron, molybdenum |
Smältpunkt | 1390-1440°C |
Täthet | 8,2 g/cm3 |
Styrka | Excellent strength from cryogenic to 1095°C temperatures |
Motståndskraft mot korrosion | Resistant to variety of corrosive environments |
Termisk stabilitet | Retains strength and corrosion resistance at elevated temperatures |
Additive Manufacturability | Optimized particle size distribution and morphology for AM processes |
Nickel Alloy HX-pulver kan användas för att tillverka komplexa komponenter med nätform med hjälp av additiva tillverkningsprocesser med pulverbäddsfusion som selektiv lasersmältning (SLM) och elektronstrålesmältning (EBM). Dess egenskaper gör den lämplig för delar som kräver hög hållfasthet, värmebeständighet och korrosionsbeständighet inom en rad olika branscher som flyg, olja och gas, fordonsindustri och allmän industri.
Legeringssystemet gör det möjligt att skräddarsy egenskaperna genom värmebehandling. Lösningsglödgning följt av åldring gör det möjligt att optimera hållfasthet, duktilitet och sprickmotstånd enligt applikationskraven.
Overall, Nickel Alloy HX presents an advanced engineering material system enabling next-generation component designs through additive manufacturing.
Sammansättning
The composition of Nickel Alloy HX powder provides an optimal balance of properties for high performance engineering components:
Nickel Alloy HX Powder Composition
Element | Vikt % | Roll |
---|---|---|
Nickel | 50-55% | Primary element providing corrosion resistance and high temperature strength |
Krom | 15-20% | Enhances oxidation and corrosion resistance |
Järn | Balans | Contributes to high strength and hardness |
Molybden | 8-10% | Solid solution strengthener, improves creep resistance |
Titanium + Aluminium | 3-4% total | Carbide formers for precipitation strengthening |
Kol | <0,05% | Hårdmetallformare |
The high nickel and chromium content imparts excellent corrosion and oxidation resistance. Solid solution strengthening elements like molybdenum along with precipitates from titanium, aluminum and carbon enable strength levels over a wide temperature range from cryogenic to 1095°C.
Tailoring of titanium and aluminum levels allows adjusting the volume fraction and type of precipitates to optimize strength and crack resistance as per specific component requirements.
Fastigheter
Nickel Alloy HX powder has a unique combination of mechanical properties, corrosion resistance, and thermal capability making it suitable for critical application components:
Nickel Alloy HX Powder Properties
Fastighet | Beskrivning |
---|---|
Täthet | 8,2 g/cm3 |
Smältintervall | 1390-1440°C |
Styrka | Ultimate Tensile Strength 130-160 ksi<br>Yield Strength 115-130 ksi |
Töjning | 15-25% |
Hårdhet | 32-36 HRC |
Slagseghet | 50-80 ft-lbs |
Termisk konduktivitet | 9-12 W/m-K |
Koefficient för termisk expansion | 12-13 x 10<sup>-6</sup>/°C |
Max driftstemperatur | 1095°C |
Motståndskraft mot korrosion | Excellent in various environments |
Oxideringsbeständighet | Resistant to 1095°C |
Termisk utmattningshållfasthet | Superior thermal fatigue life |
Termisk stabilitet | Retains strength at elevated temperatures |
Notch Sensitivity | Low notch sensitivity |
The fine powder morphology and optimized particle size distribution allows high density (>99.5%) components to be printed using nickel alloy HX powder. This enables realizing the alloy’s full potential in terms of mechanical properties and performance.
Solution heat treatment followed by aging heat treatment allows tailoring strength vs ductility levels as per specific component design requirements. For maximum strength, aging at 720°C for 16 hours is typically used.
Tillämpningar
The combination of properties of Nickel Alloy HX powder makes it suitable for variety of demanding applications across industries:
Industries Using Nickel Alloy HX Powder
- Flyg- och rymdindustrin
- Olja och gas
- Fordon
- Industriell
Component Applications
- Combustion cans
- Bushing housings
- Valves and valve bodies
- Piston parts
- Pumping components
- Printed heat exchangers
- Fluid handling parts
- Tooling inserts
The excellent high temperature strength enables lighter weight components closer to the heat source like combustor cans, nozzle components, bleed valves etc. in next-generation aerospace engines.
The corrosion resistance allows use in oil field components like valves, pumps and downhole tools. Resistance to sour service environments expands applicability across oil and gas applications.
In automotive, high temperature valves, pumps, turbocharger components are enabled by the alloy’s thermal capability and dimensional stability.
Additive manufacturing using nickel alloy HX powder is also enabling optimized heat exchangers, lightweight flanges, housings with integrated channels and cooling features across industries.
Specifikationer
Nickel alloy HX powder is supplied by leading manufacturers like Carpenter Additive, Sandvik Osprey, Erasteel, Praxair Surface Technologies etc. It meets the following powder specifications:
Nickel Alloy HX Powder Specifications
Parameter | Specifikation |
---|---|
Pulversammansättning | <2% variation from nominal |
Partikelstorlek | 15-53 mikrometer |
Skenbar densitet | Typically > 4.0 g/cm3 |
Hall Flow Rate | <30s/50g |
Fukthalt | <0.1 wt% |
The particle size distribution allows spreading thin powder layers and achieving near fully dense parts after melting. High powder flowability and apparent density provide ease of powder handling during loading and re-use.
Standarder
While no dedicated standard exists currently, Nickel Alloy HX powder specifications align with composition limits in standards for wrought forms like:
- AMS 5754
- AMS 5844
- AMS 5845
- UNS N06002
Equivalent wrought alloys include Haynes 214, Inconel 718, Waspaloy etc. As additive manufacturing usage increases, dedicated nickel alloy powder standards will emerge.
Leverantörer och prissättning
Nickel alloy HX powder is available from leading metal powder suppliers and additive manufacturing equipment OEMs:
Nickel Alloy HX Powder Suppliers
Leverantör | Beskrivning |
---|---|
Snickare Tillsats | Broadest portfolio of nickel alloy powders for AM |
Sandvik Osprey | Wide range of niche alloy powders for AM |
Erasteel | Powder metallurgy specialist with broad alloy powder expertise |
Praxair Ytteknologi | Leading supplier of metal powders for AM industry |
SLM-lösningar | Provides optimized alloy powders for its AM systems |
GE Additiv | Supplies alloy powders for healthcare, aviation and industrial AM |
Typical pricing for Nickel Alloy HX powder is in the range $$$/kg. High purity levels, extensive quality control and optimized particle characteristics account for the premium pricing of this advanced alloy powder.
Cost Comparison With Alternatives
Legeringspulver | Indikativ prissättning |
---|---|
Nickel Alloy HX | $$$/kg |
Titan Ti64 | $$/kg |
Aluminium AlSi10Mg | $/kg |
Rostfritt stål 316L | $$/kg |
Pricing varies between suppliers based on order quantity, quality requirements and geographical factors. Bulk order discounts may apply on orders over 500-1000 kg.
Fördelar och begränsningar
Nickel Alloy HX presents some clear advantages along with certain limitations:
Fördelar
- Excellent mechanical properties from cryogenic to 1095°C temperatures
- Retains strength and corrosion resistance at elevated temperatures
- Resists variety of corrosive environments
- Thermal fatigue and oxidation resistance up to 1095°C
- Låg värmeutvidgningskoefficient
- Additive manufacturability using PBF processes
- Parts can be heat treated to tailor properties
Begränsningar
- High material cost compared to steels
- Lower tensile elongation limits ductility
- Requires hot isostatic pressing (HIP) to eliminate internal porosity
- Limited number of alloy powder suppliers currently
- Parameter development needed for new additive systems
For components demanding performance under thermal and mechanical loads in corrosive environments, the advantages of nickel alloy HX outweigh limitations of cost and ductility.
Qualification and Printing
Qualifying new materials like Nickel Alloy HX powder for additive manufacturing involves extensive characterization and process development:
Nickel Alloy HX Powder Qualification
- Chemical analysis – Confirm composition conformity to specification via wet chemistry or OES
- Particle size distribution – Validate powder sphericity and size parameters using laser diffraction
- Apparent density and flow measurements – Check suitability for powder spreading using Hall flowmeter as per ASTM B213 standard
- Internal porosity assessment – Analyze density uniformity and internal defects using microCT scans
- Microstructure characterization – Use SEM and EDS to evaluate alloy uniformity, precipitation and defects
- Process parameter development – Optimize laser power, speed, hatch spacing for density >99.5% using test cubes
- Mechanical testing – Perform tensile, fatigue, fracture toughness, creep on AM test parts and compare to wrought properties
- Non-destructive evaluation – Use techniques like dye-penetrant testing to identify surface/sub-surface defects
- Corrosion testing – Evaluate corrosion rate in relevant environments through immersion testing or ASTM standards
- Post-processing – Study effect of hot isostatic pressing (HIP) and heat treatment on properties
- Application demonstration – Fabricate real component prototypes and measure functional performance against design targets
This extensive testing validates the alloy powder quality and its suitability for printing application components meeting the required property targets.
Print Parameter Guidelines
Typical parameters for printing Nickel Alloy HX powder on SLM 125HL system from SLM Solutions:
Parameter | Typiskt värde |
---|---|
Skiktets tjocklek | 30-50 μm |
Laserkraft | 175-350 W |
Skanningshastighet | 125-250 mm/s |
Avstånd mellan luckor | 80-120 μm |
Stripe overlap | 50% |
Powder bed temp | 80-100°C |
Parameters vary based on factors like desired properties, surface finish, build rate priorities and AM system capabilities. Parameter sets get continually refined through rigorous DOE approaches to expand printable geometry and property range.
Efterbearbetning
Common post-processing steps for additively manufactured Nickel Alloy HX components include:
- Removal from build plate – Wire EDM or band saw cutting to remove parts from plate
- Stöd för borttagning – Carefully remove auto-generated supports mechanically or using EDM
- Stresslindring – Heat component uniformly to 620°C for 1-2 hours to relieve residual stresses
- Varm isostatisk pressning – HIP at 1160°C/100-200 MPa for 4 hours to eliminate internal porosity >98% density
- Ytbehandling – Abrasive flow machining and media blasting enhances surface finish
- Dimension measurement – Confirm critical dimensions using CMM inspection and scan for geometric accuracy
- Dye-penetrant testing – Check for surface breaking flaws needing repair using fluorescent or visible dye penetrants
- Värmebehandling – Solution treat 1120°C, rapid air cool + age 720°C/16 hrs for desired properties
Automating post-processing operations is crucial considering geometric complexity of additively manufactured components using Nickel Alloy HX powder.
Careful design and support strategies are also vital during pre-processing to improve downstream efficiency. Periodic inspection should validate all design and certification requirements are being met.
Applications and Case Studies
Nickel Alloy HX is being applied across demanding application areas:
Flyg- och rymdindustrin
- Combustor cans – 40% weight reduction, handles 100°C higher temperatures
- Commercial jet bleed valve housing – Integrated cooling channels, optimized fluid flow
- Satellite thruster chambers – High strength-to-weight ratio, reusable
Olja och gas
- Sour gas valve bodies – Corrosion resistant nickel alloy withstands H2S environment
- Downhole safety valve components – Withstands 150°C temperatures and erosion
- Offshore pump impeller – Lightweight, efficient fluid handing under seawater
Fordon
- Turbocharger compressor wheel – High speed capability to 110,000 rpm
- Exhaust control valve – Handles exhaust gas temperatures up to 1050°C
- Piston crown – Conformal cooling channels enable higher power density engine
Industriell
- Continuous casting nozzle – High temperature fluid flow device boosts steel plant productivity
- Extrusion press tooling – Improved durability and double the life
- Printing press heating element – Integrated nickel alloy circuit handles 700°C temperatures
These application examples showcase the potential of Nickel Alloy HX to push performance boundaries across industries through additive techniques. More widespread availability of parameter data and demonstrations will further expand adoption.
Vanliga frågor
Q: What are the main advantages Nickel Alloy HX offers over conventional materials?
Nickel Alloy HX provides an exceptional combination of high strength up to 1095°C along with toughness and corrosion resistance not achievable with typical alloys. Additive manufacturability enables designs not possible with subtractive techniques.
Q: What heat treatment is used for Nickel Alloy HX AM parts?
Solution treatment at 1120°C followed by aging at 720°C for 16 hrs enables an excellent balance of strength (>150 ksi UTS) and ductility (>16% El.). HIP is applied post-build and prior to heat treatment.
Q: What AM process is ideal for nickel alloy HX powder?
Selective laser melting (SLM) is preferred over Electron Beam Melting for Nickel Alloy HX to better control thermal stresses and cracking. SLM allows higher density while controlling directional properties.
Q: What industries offer the best opportunities for Nickel Alloy HX AM adoption?
Aerospace, oil and gas, automotive and industrial heat treatment industries are adopting nickel alloy HX for components demanding thermal stability, strength and corrosion performance.
Q: Does Nickel Alloy HX require any special powder handling or storage precautions?
Nickel alloy powders are not hazardous though respiratory and explosion precautions are prudent as with any fine metal powder. Argon inert storage with moisture controls preserves long term reusability.
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